NMR studies of group 8 metallodrugs:187Os-enriched organo-osmium half-sandwich anticancer complex

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Russell J. Needham; Ivan Prokes; Abraha Habtemariam; Isolda Romero-Canelon; Guy J. Clarkson; Peter J. Sadler

doi:10.1039/d1dt02213j

NMR studies of group 8 metallodrugs:¹⁸⁷Os-enriched organo-osmium half-sandwich anticancer complex

Russell J. Needham & Peter J. Sadler et al. · 2021-09-28

Synthesis of this¹⁸⁷Os-enriched organo-osmium azopyridine anticancer complex, has allowed determination of¹⁸⁷Os NMR J-couplings to ligand¹H and¹³C, and the¹⁸⁷Os chemical shift. The complex was also characterised by X-ray crystallography and MS.

NMR studies of group 8 metallodrugs:187Os-enriched organo-osmium half-sandwich anticancer complex

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NMR studies of group 8 metallodrugs:¹⁸⁷Os-enriched organo-osmium half-sandwich anticancer complex